Hi Keith,
Thank you for contacting the Microsoft Community.
Allow me to assist you to eliminate the error message you are receiving when using your outlook account.
I checked and found that the “The selected user account does not exist in the Microsoft Services tenant and cannot access the application in that tenant” error you are receiving means that the account must first be added to the tenant as an external user. Please make sure that the work email address will be added on your tenant to eliminate the error.
For further assistance on this matter, please contact your organization’s IT, or the department that manages your company’s Azure Active Directory. If you are using a work unit, please try using a personal one to eliminate site cookies and restrictions. You may also check this link for reference on the error code.
You may also try to use Edge Chromium In-private or Chrome Incognito browser and allow all third party cookies through the browser settings.
If the issue persists after following my resolution recommendation, please send us a steps-by-steps recording using this Problem Steps Recorder (PSR). You may start from the login page until the error message appears and secure it via private message along with the requested information so I can continue troubleshooting with you.
I look forward to your response. Please note that if no response is received after two business days, the case will be closed and locked. After the case is locked, we will no longer be able to respond, even through Private Messages. Thank you.